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Sodium Isobutyl Xanthate

Sodium Isobutyl Xanthate (Chemical formula: C₅H₉NaOS₂, CAS:25306-75-6), also known as sodium O-isobutyl dithiocarbonate, is a light-yellow to grayish-white powder or granule with a pungent odor, soluble in water and alcohol.

It serves as a potent collector in the flotation of non-ferrous metal sulfide ores (e.g., copper, lead, zinc), particularly effective for mixed or preferential separation of chalcopyrite, sphalerite, and pyrite.

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Sodium Isobutyl Xanthate (Chemical formula: C₅H₉NaOS₂, CAS:25306-75-6), also known as sodium O-isobutyl dithiocarbonate, is a light-yellow to grayish-white powder or granule with a pungent odor, soluble in water and alcohol. 

It serves as a potent collector in the flotation of non-ferrous metal sulfide ores (e.g., copper, lead, zinc), particularly effective for mixed or preferential separation of chalcopyrite, sphalerite, and pyrite. 

Its collecting power surpasses ethyl and isopropyl xanthates, enhancing the selectivity between sulfide ores and gangue minerals under optimized conditions.The production process utilizing carbon disulfide as an in-situ solvent achieves high purity (≥90%) and yield (≥95%), offering advantages in energy efficiency and environmental compatibility compared to conventional methods.

Parameter

Description

Value

Chemical Formula

The molecular formula

Cu₂H₄N₂OS₂

CAS Number

Chemical Abstracts Service registry number

25306-75-6

Molecular Weight

The mass of one molecule of the compound

172.24 g/mol

Appearance

Physical state and color

Light yellow to grayish-white powder or granules

Odor

Smell characteristic

Pungent odor

Solubility in Water

Solubility at room temperature

Soluble

Density

Mass per unit volume

Approx. 1.1 g/cm³ (granular form)

Melting Point

Temperature at which it changes from solid to liquid

Decomposes before melting

Boiling Point

Temperature at which it changes from liquid to gas

Not applicable (decomposes)

pH

Measure of acidity or basicity

Approximately 10-11 (1% solution)

Flash Point

The lowest temperature at which it can vaporize to form an ignitable mixture in air

Not applicable (non-flammable)

Stability

Conditions under which the compound is stable

Stable under normal temperatures and pressures, sensitive to moisture

Toxicity

The degree to which a substance can damage an organism

Toxic if inhaled or ingested, can cause skin and eye irritation

Sodium isobutyl xanthate (SIBX) has the following primary applications:

(1) Flotation Collector for Sulfide Ores: It serves as a strong and selective collector in the flotation of non-ferrous metal sulfide ores, including copper, lead, zinc, and pyrite. Its efficacy is particularly notable in separating copper sulfides from iron sulfides and recovering activated zinc sulfide ores.

(2) Precipitating Agent in Hydrometallurgy: It is utilized to purify metal ions (e.g., cobalt, copper, nickel) in hydrometallurgical processes, such as zinc electrolyte purification, by forming insoluble complexes with target metal ions.

(3) Rubber Vulcanization Accelerator: As a derivative of xanthates, it acts as a vulcanization accelerator in the rubber industry to enhance the cross-linking efficiency during rubber processing. These applications leverage its chemical reactivity with metal ions and its role in industrial separation and material synthesis processes.

(1) Packaging Requirements: Use hermetically sealed, corrosion-resistant containers (e.g., polyethylene-lined drums or airtight plastic bags) to prevent oxidation and moisture ingress. - Clearly label containers with hazard warnings (e.g., “Flammable Solid,” “Keep Dry”) and regulatory information (CAS No.25306-75-6).

(2)Storage Conditions: Store in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Maintain ambient temperature below25°C. - Isolate from incompatible substances, including strong acids, oxidizers, and water-reactive materials.

(3) Handling Precautions: Avoid physical damage to containers to prevent leakage or dust formation. - Implement grounding measures during transfer to mitigate electrostatic discharge risks.

(4) Stability and Shelf Life: Monitor for decomposition signs (e.g., discoloration, odor changes). Degradation products may include carbon disulfide and other hazardous compounds. Limit long-term storage; prioritize first-in, first-out (FIFO) inventory management.

(5)Safety Compliance: Adhere to local regulations for flammable solids (UN3342, Hazard Class4.2) during transportation and storage. - Equip storage areas with spill containment systems and fire suppression equipment (e.g., dry chemical extinguishers).

These guidelines ensure chemical integrity and minimize risks of combustion, hydrolysis, or unintended reactions.

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